Synthesis and Photochromism studies of 1-(2-methyl-3- benzothiophene)-2-[2-methyl-5-pyrenyl-3-thienyl] perfluorocyclopentene
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چکیده
منابع مشابه
Synthesis and Properties Study of 1-(2,4-dimethoxyl-5-pyrimidinyl)-2-[2-methyl-5- (3-methyl)-phenyl-3-thienyl] Perfluorocyclopentene
A novel photochromic diarylethene bearing a pyrimidine moiety, 1-(2,4-dimethoxyl-5-pyrimidinyl)-2-[2methyl-5-(3-methyl)-3-thienyl]perfluorocyclopentene has been synthesized. Its properties, including photochromic and fluorescent behaviors, have been investigated. The compound exhibited remarkable photochromism, changing from colorless to red after irradiation with UV light in solution. The cycl...
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In this manuscript, we describe the synthesis of the carbohydrazide 2. Acid-catalyzed condensation with several carbonyl compounds to afford the corresponding carbohydrazide derivatives 3-12. Their acetylation afforded the corresponding acetyl derivatives 13-22. Oxidative cyclization of O-acetyl derivatives 19-22 afforded the corresponding 1,3,4-oxadiazole derivatives 23-2...
متن کامل2-Amino-4-methyl-4,5,6,7-tetrahydro-1-benzothiophene-3-carbonitrile
In the title compound, C(10)H(12)N(2)S, the thio-phene ring is essentially planar (r.m.s. deviation = 0.0290 Å). The two C atoms of the cyclo-hexene ring (at positions 6 and 7) are disordered over two sets of sites in a 0.810 (5):0.190 (5) ratio. The cyclo-hexene rings in both the major and minor occupancy conformers adopt a half-chair conformation. In the crystal, there are two types of N-H⋯N ...
متن کامل3-(4-{3,3,4,4,5,5-Hexafluoro-2-[5-(3-methoxyphenyl)-2-methyl-3-thienyl]cyclopent-1-enyl}-5-methyl-2-thienyl)benzonitrile
The title compound, C(29)H(19)F(6)NOS(2), is a new unsymmetrical photochromic diarylethene derivative with different meta-phenyl substituents. The distance between the two reactive (i.e. can be irradiated to form a new chemical bond) C atoms is 3.501 (4) Å; the dihedral angles between the mean plane of the main central cyclo-pentene ring and the thio-phene rings are 47.7 (5) and 45.1 (2)°, and ...
متن کاملSynthesis and Properties of a Novel Diarylethene 1-(2-cyano-1,5-dimethyl-4-pyrryl)- 2-{(2-methyl-4-hydroxymethylphe-nyl)-3-thienyl} Perfluorocyclopentene
An asymmetrical photochromic diarylethene 1-(2cyano-1,5-dimethyl-4-pyrryl)-2-{(2-methyl-4hydroxymethylphe -nyl)-3-thienyl}perfluorocyclopentene (1o) was synthesized and its photochromic properties as well as reaction kinetics were investigated in detail. Upon irradiation with 297 nm UV light, diarylethene 1o exhibited photochromism in solution. Moreover, 1o also exhibited obviously fluorescence...
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ژورنال
عنوان ژورنال: DEStech Transactions on Materials Science and Engineering
سال: 2017
ISSN: 2572-889X
DOI: 10.12783/dtmse/icmea2015/7272